首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   9488篇
  免费   773篇
  国内免费   195篇
化学   2626篇
晶体学   27篇
力学   763篇
综合类   285篇
数学   4541篇
物理学   2214篇
  2024年   4篇
  2023年   96篇
  2022年   248篇
  2021年   341篇
  2020年   274篇
  2019年   214篇
  2018年   222篇
  2017年   381篇
  2016年   378篇
  2015年   265篇
  2014年   553篇
  2013年   648篇
  2012年   519篇
  2011年   555篇
  2010年   400篇
  2009年   558篇
  2008年   510篇
  2007年   533篇
  2006年   500篇
  2005年   421篇
  2004年   372篇
  2003年   281篇
  2002年   269篇
  2001年   274篇
  2000年   205篇
  1999年   186篇
  1998年   157篇
  1997年   150篇
  1996年   154篇
  1995年   110篇
  1994年   75篇
  1993年   68篇
  1992年   44篇
  1991年   45篇
  1990年   32篇
  1989年   36篇
  1988年   29篇
  1987年   28篇
  1986年   15篇
  1985年   66篇
  1984年   59篇
  1983年   24篇
  1982年   45篇
  1981年   43篇
  1980年   30篇
  1979年   22篇
  1978年   7篇
  1977年   3篇
  1971年   2篇
  1959年   2篇
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
1.
在砂土地层中,串囊式充气锚杆的研究还比较少,其承载特性及受力机理尚不明确。本文基于莫尔-库仑模型和Vesic圆孔扩张理论法,分别对圆柱体、球体、组合体、椭球体假设下的串囊式充气锚杆的扩大段进行计算分析。并将计算结果与试验得到的实测值进行对比。结果表明:四种形状假设中椭球体的形状假设理论值与实测值的误差最小,仅为8.35%。通过拟合试验数据,并引入与端阻力和侧摩阻力有关的两个系数对承载力公式进行修正,得到了抗拔承载力的经验公式。  相似文献   
2.
针对公众参与的语言信息多属性群决策问题,研究了考虑参与者满意度的概率语言多属性群决策方法。首先,根据参与者的语言评价信息确定并规范化概率语言决策矩阵。然后,对大群体进行共识分析,由最大化参与者群体的满意度构建线性规划模型,确定参与者群组的权重;构造正、负理想方案的评价向量,构建多目标规划模型,用拉格朗日乘子法求解属性权重;定义各方案的加权贴近度,并以此对方案进行排序和优选。最后,通过新型智慧城市市民获得感评价案例验证了模型的可行性和有效性。  相似文献   
3.
This paper addresses the challenges of creating realistic models of soil for simulations of heavy vehicles on weak terrain. We modelled dense soils using the discrete element method with variable parameters for surface friction, normal cohesion, and rolling resistance. To find out what type of soils can be represented, we measured the internal friction and bulk cohesion of over 100 different virtual samples. To test the model, we simulated rut formation from a heavy vehicle with different loads and soil strengths. We conclude that the relevant space of dense frictional and frictional-cohesive soils can be represented and that the model is applicable for simulation of large deformations induced by heavy vehicles on weak terrain.  相似文献   
4.
独立高校数学课程的开设旨在让学生掌握数学知识的基础上,提高数学应用能力.然而现行的考核方式存在重考试结果,轻学习过程等问题.从传统考核方式入手,指出其不足之处,基于模糊综合评判法建立新型评价体系和数学模型,通过试点运行验证了新的考核方式的可行性、客观性、合理性和科学性.  相似文献   
5.
Dong-Yang Liu 《中国物理 B》2022,31(12):128104-128104
Regulation of oxygen on properties of moderately boron-doped diamond films is fully investigated. Results show that, with adding a small amount of oxygen (oxygen-to-carbon ratio < 5.0%), the crystal quality of diamond is improved, and a suppression effect of residual nitrogen is observed. With increasing ratio of O/C from 2.5% to 20.0%, the hole concentration is firstly increased then reduced. This change of hole concentration is also explained. Moreover, the results of Hall effect measurement with temperatures from 300 K to 825 K show that, with adding a small amount of oxygen, boron and oxygen complex structures (especially B3O and B4O) are formed and exhibit as shallow donor in diamond, which results in increase of donor concentration. With further increase of ratio of O/C, the inhibitory behaviors of oxygen on boron leads to decrease of acceptor concentration (the optical emission spectroscopy has shown that it is decreased with ratio of O/C more than 10.0%). This work demonstrates that oxygen-doping induced increasement of the crystalline and surface quality could be restored by the co-doping with oxygen. The technique could achieve boron-doped diamond films with both high quality and acceptable hole concentration, which is applicable to electronic level of usage.  相似文献   
6.
于颖敏 《化学教育》2019,40(12):24-28
设计了以柴油中饱和烃含量及碳数分布测定、聚丙烯酸高级醇酯(PTA)的合成与纯化、PTA的红外表征与分子量测定、PTA降凝性能评价等4个模块组成的综合实验,作为化工专业实验的考核及成绩评定平台。这种考核方式将过程考核与结果考核融合,将笔试、操作、设计融合,可以全面准确地考核学生的有机合成、仪器分析等基础实验技能,同时考核综述、数据处理、实验设计等综合实验能力和实验室工作素质。此外,还能够有效训练学生的学习能力、解决问题能力、实践能力和创新能力,并促进了实验教学水平提高。  相似文献   
7.
将专业综合实验与科研成果相结合,设计了新型表面活性剂的合成与表征综合化学实验。实验涉及含羟基基团的表面活性剂的合成、纯化、结构表征和性能测定等操作。该综合实验将有机化学基础知识、表面活性剂的基本性质与前沿科学研究相结合,从而实现学生实验技能的提升、认知视野的拓展和综合能力培养的目标。  相似文献   
8.
The effects of moderate thermosonication (MTS) on the quality quartet: physico-chemical, microbial, nutritional and sensory qualities of orange juice (OJ) inoculated with Alicyclobacillus acidoterrestris (AAT) were studied during 24 days of storage at ambient and refrigerated temperatures. The bioactive compounds and antioxidant activity of OJ decreased with storage, while the pectin methyl esterase (PME) increased. Nonetheless, noticeable changes were observed from the 12th day of storage. There was no obvious (p > 0.05) variation in pH and total soluble solids. To determine the nutritional and microbial quality characteristics of OJ during storage, non-linear kinetic curves were successfully fitted with least square fitting polynomial and four-parameter log-logistic distribution models. The E-nose sensors succeeded in discriminating between the aroma of non-treated and treated OJ based on linear discriminant analysis (LDA). Furthermore, terpenes, alcohol and partially aromatic compounds were the main spoilage indicators of OJ during storage based on E-nose analysis and confirmed by HS-SPME-GC/MS analysis. Thus, MTS significantly extended the shelf life of the quality quartet of natural OJ at 4 °C. E-nose-GC/MS fusion offered odor fingerprints to AAT microorganisms that can be used as spoilage index without using traditional food analysis techniques. The proposed approach can be used as an alternative tool for rapid detection of spoilage microorganisms in OJ.  相似文献   
9.
为系统地验证复合材料失效判据计算精度和有效性范围,给出了4种材料体系、6种铺层形式的层合板在单轴、双轴载荷下的失效试验数据,用以评估复合材料失效判据在单向层合板失效包线、多向层合板初始失效包线、多向层合板最终失效包线、层合板变形及层合板的破坏特性等五个方面的预测能力。并根据验证方法和有效性评估策略对失效判据计算精度进行量化考核,给出了失效判据在五个层面上的计算精度。  相似文献   
10.
The dissipation dynamic and residues of spiroxamine in open-field-grown strawberries were determined using liquid chromatography tandem mass spectrometry (LC–MS/MS). Spiroxamine application was performed according to Egyptian good agricultural practices recommendation. A QuEChERS-based extraction method along with direct analysis with an LC–MS/MS analytical method were optimized and validated, and the specificity of the techniques used was considered satisfactory. Good linearity (R2 > 0.999) was obtained for spiroxamine within the range of 0.001–0.1 μg/ml. The mean recoveries varied between 97.1 and 108.2%, with inter- and intra-day precision (RSD) <4.9%. The limit of quantitation for spiroxamine was 0.001 mg/kg. The results indicated that spiroxamine degradation in strawberry followed first–order kinetics (R2 > 0.9929) with an estimated half-life value of 4.71 days. Considering the Australian maximum residue limit (0.05 mg/kg) in strawberry and based on the results from residue trials with a preharvest interval of 14 days for strawberry, compliance can be expected. The present results could provide guidance to fully evaluate the risks of spiroxamine residues, preventing any potential health risk to consumers.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号